Northern Ireland, Scotland, Wales, most of the Midlands and western England were already under yellow warnings for wind on Sunday, with travel delays and power cuts expected.
But a new amber warning has been issued for rain in south and central Wales which will be in force from 3pm on Sunday to 6am on Monday.
Winds across the west of the UK will increase throughout the morning with gusts up to 70mph in exposed areas, the Met Office said.
This is a breaking news story and is being updated.
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